Ing. Juan Ojea Espil.

Presentación del tema: "Ing. Juan Ojea Espil."— Transcripción de la presentación:

1 Ing. Juan Ojea Espil

2 Diferencia entre Normas Voluntarias y Obligatorias
Las Normas Obligatorias se encuentran por encima de las Normas Voluntarias Para las Normas Voluntarias: La temática se desarrolla a partir de una demanda de mercado puntual. En su elaboración intervienen las partes interesadas. Se adoptan por consenso (no se trata de una votación, sino que implica la no existencia de una posición contraria sostenida) El proceso de desarrollo incluye el periodo en el cual deberá ser revisada (por ejemplo, revisiones cada 3 o 5 años), adecuándola siempre a las exigencias y realidades del mercado actual.

3 Normalización en General
Las Normas Voluntarias son determinantes en el comercio internacional de bienes y servicios, ya que sus requisitos reflejan las necesidades y expectativas de los consumidores, induciendo también las exigencias de los usuarios. Las Normas Voluntarias permiten aprovechar economías de escala y encadenamientos productivos, logrando que las empresas del bloque comercial puedan competir eficientemente en los mercados externos. Actualmente las organizaciones reconocen las ventajas de la implementación de normas de cumplimiento voluntario para el logro de la competitividad.

4 Principios de la normalización
Participación Transparencia Consenso Coherencia Técnica Sector Consumo Sector Privado Interés General

5 Niveles de la Normalización
ISO IEC - ITU COPANT – AMN CEN - CENELEC DIN – AFNOR- ANSI IRAM - AENOR - INTN API – ASTM- SAE- ASME EMPRESAS

6 Normalización internacional
Miembro O

7 ISO/TC 147 – Water quality Alcance
Normalizar en el campo de la calidad el agua, incluyendo términos y definiciones, muestreo de aguas, medición, análisis e informe de las características del agua. Queda excluido del alcance la determinación de los limites de calidad del agua.

8 Subcomités del TC 147 – Calidad del agua
TC 147/SC 1 Terminology TC 147/SC 2 Physical, chemical and biochemical methods TC 147/SC 4 Microbiological methods TC 147/SC 5 Biological methods TC 147/SC 6 Sampling (general methods) Total de normas ISO publicadas por el TC y sus SC: 234 Paises Participantes: 32 Paises Observadores: 51

9 Organigrama ISO/TC 147 - Water Quality Secretariat: DIN
SC2 Physical, chemical and biochemical methods (DIN) SC1 Terminology (SABS) WG 17 Phenols WG 19 Polycyclic aromatic hydrocarbons (PAH) SC4 Microbiological methods (DIN) WG 32 ICP techniques WG 33 Ion chromatography methods WG 38 Flow analysis methods WG 45 Dioxins WG 2 Coliforms (E. coli and other coliforms) WG 5 Sulfite reducing clostridium WG 47 Microcystins WG 48 Precision and accuracy WG 7 Salmonella WG 10 Legionella WG 49 Bromophenylethers WG 52 Antimony, arsenic and selenium WG 12 Analytical quality control of microbiological media WG 13 Cryptosporidium/Giardia WG 53 GC-MS for groups of non-polar substances WG 54 Alkalinity in marine water WG 15 Enumeration of microorganisms by culture WG 16 Sampling for microbiological analysis WG 55 Glyphosate and AMPA WG 56 PFOS and PFOA SC5 Biological methods SC6 Sampling (general methods) WG 1 Toxicity - Bacteria and biodegradability WG 1 Design of sampling programmes (Revision of ISO ) WG 2 Toxicity to invertebrates WG 3 Conservation methods WG 5 Toxicity - Algae and aquatic plants WG 6 Drinking water and water used for food and beverage WG 3 Toxicity - Fish WG 4 Rivers and streams including groundwater WG 6 Biological classification WG 9 Genotoxicity WG 11 Sampling of sludges and sediments

10 TC 147/SC 1 Terminology ISO 6107-1:2004 Water quality -- Vocabulary
ISO :1993/Amd 1:2001 ISO :1993 Water quality -- Vocabulary ISO :2004 Water quality -- Vocabulary ISO :2004 Water quality -- Vocabulary ISO :2006 Water quality -- Vocabulary ISO :1993 Water quality -- Vocabulary ISO :1993/Amd 1:2001 ISO :1997 Water quality -- Vocabulary -- Part 9: Alphabetical list and subject index

11 ISO 5666:1999 Water quality -- Determination of mercury
TC 147/SC 2 Physical, chemical and biochemical methods ISO 5663:1984 Water quality -- Determination of Kjeldahl nitrogen -- Method after mineralization with selenium ISO 5664:1984 Water quality -- Determination of ammonium -- Distillation and titration method ISO 5666:1999 Water quality -- Determination of mercury ISO 5813:1983 Water quality -- Determination of dissolved oxygen -- Iodometric method ISO 5814:1990 Water quality -- Determination of dissolved oxygen -- Electrochemical probe method ISO :2003 Water quality -- Determination of biochemical oxygen demand after n days (BODn) -- Part 1: Dilution and seeding method with allylthiourea addition ISO :2003 Water quality -- Determination of biochemical oxygen demand after n days (BODn) -- Part 2: Method for undiluted samples ISO 5961:1994 Water quality -- Determination of cadmium by atomic absorption spectrometry ISO 6058:1984 Water quality -- Determination of calcium content -- EDTA titrimetric method ISO 6059:1984 Water quality -- Determination of the sum of calcium and magnesium -- EDTA titrimetric method ISO 6060:1989 Water quality -- Determination of the chemical oxygen demand

12 ISO 7027:1999 Water quality -- Determination of turbidity
ISO 6332:1988 Water quality -- Determination of iron -- Spectrometric method using 1,10-phenanthroline ISO 6333:1986 Water quality -- Determination of manganese -- Formaldoxime spectrometric method ISO 6439:1990 Water quality -- Determination of phenol index -- 4-Aminoantipyrine spectrometric methods after distillation ISO 6468:1996 Water quality -- Determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes -- Gas chromatographic method after liquid-liquid extraction ISO :1984 Water quality -- Determination of cyanide -- Part 1: Determination of total cyanide ISO :1984 Water quality -- Determination of cyanide -- Part 2: Determination of easily liberatable cyanide ISO :1984 Water quality -- Determination of cyanide -- Part 3: Determination of cyanogen chloride ISO 6777:1984 Water quality -- Determination of nitrite -- Molecular absorption spectrometric method ISO 6778:1984 Water quality -- Determination of ammonium -- Potentiometric method ISO 6878:2004 Water quality -- Determination of phosphorus -- Ammonium molybdate spectrometric method ISO 7027:1999 Water quality -- Determination of turbidity

13 ISO 7887:1994 Water quality -- Examination and determination of colour
ISO :1984 Water quality -- Determination of ammonium -- Part 1: Manual spectrometric method ISO :1985 Water quality -- Determination of free chlorine and total chlorine -- Part 1: Titrimetric method using N,N-diethyl-1,4-phenylenediamine ISO :1985/Cor 1:2001 ISO :1985 Water quality -- Determination of free chlorine and total chlorine -- Part 2: Colorimetric method using N,N-diethyl-1,4-phenylenediamine, for routine control purposes ISO :1990 Water quality -- Determination of free chlorine and total chlorine -- Part 3: Iodometric titration method for the determination of total chlorine ISO :1996 Water quality -- Determination of surfactants -- Part 1: Determination of anionic surfactants by measurement of the methylene blue index (MBAS) ISO :1996/Cor 1:2003 ISO :1984 Water quality -- Determination of surfactants -- Part 2: Determination of non-ionic surfactants using Dragendorff reagent ISO 7887:1994 Water quality -- Examination and determination of colour ISO 7888:1985 Water quality -- Determination of electrical conductivity ISO :1988 Water quality -- Determination of nitrate -- Part 3: Spectrometric method using sulfosalicylic acid ISO 7980:1986 Water quality -- Determination of calcium and magnesium -- Atomic absorption spectrometric method

14 ISO 8467:1993 Water quality -- Determination of permanganate index
ISO :2005 Water quality -- Determination of polycyclic aromatic hydrocarbons (PAH) -- Part 1: Determination of six PAH by high-performance thin-layer chromatography with fluorescence detection after liquid-liquid extraction ISO :2005 Water quality -- Determination of polycyclic aromatic hydrocarbons (PAH) -- Part 2: Determination of six PAH by high-performance liquid chromatography with fluorescence detection after liquid-liquid extraction ISO :1992 Water quality -- Determination of selected monovalent phenols -- Part 1: Gas-chromatographic method after enrichment by extraction ISO :1999 Water quality -- Determination of selected monovalent phenols -- Part 2: Method by derivatization and gas chromatography ISO 8245:1999 Water quality -- Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) ISO 8288:1986 Water quality -- Determination of cobalt, nickel, copper, zinc, cadmium and lead -- Flame atomic absorption spectrometric methods ISO :1990 Water quality -- Calibration and evaluation of analytical methods and estimation of performance characteristics -- Part 1: Statistical evaluation of the linear calibration function ISO :2001 Water quality -- Calibration and evaluation of analytical methods and estimation of performance characteristics -- Part 2: Calibration strategy for non-linear second-order calibration functions ISO 8467:1993 Water quality -- Determination of permanganate index

15 ISO 9174:1998 Water quality -- Determination of chromium -- Atomic absorption spectrometric methods
ISO 9297:1989 Water quality -- Determination of chloride -- Silver nitrate titration with chromate indicator (Mohr's method) ISO :2000 Water quality -- Determination of hydrocarbon oil index -- Part 2: Method using solvent extraction and gas chromatography ISO 9390:1990 Water quality -- Determination of borate -- Spectrometric method using azomethine-H ISO 9562:2004 Water quality -- Determination of adsorbable organically bound halogens (AOX) ISO :1994 Water quality -- Determination of alkalinity -- Part 1: Determination of total and composite alkalinity ISO :1994 Water quality -- Determination of alkalinity -- Part 2: Determination of carbonate alkalinity ISO :1993 Water quality -- Determination of sodium and potassium -- Part 1: Determination of sodium by atomic absorption spectrometry ISO :1993 Water quality -- Determination of sodium and potassium -- Part 2: Determination of potassium by atomic absorption spectrometry ISO :1993 Water quality -- Determination of sodium and potassium -- Part 3: Determination of sodium and potassium by flame emission spectrometry ISO 9965:1993 Water quality -- Determination of selenium -- Atomic absorption spectrometric method (hydride technique) ISO 10260:1992 Water quality -- Measurement of biochemical parameters -- Spectrometric determination of the chlorophyll-a concentration ISO 10301:1997 Water quality -- Determination of highly volatile halogenated hydrocarbons -- Gas-chromatographic methods

16 ISO 10523:1994 Water quality -- Determination of pH
ISO :2007 Water quality -- Determination of dissolved anions by liquid chromatography of ions -- Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate ISO :1997 Water quality -- Determination of dissolved anions by liquid chromatography of ions -- Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate ISO :1997 Water quality -- Determination of dissolved anions by liquid chromatography of ions -- Part 4: Determination of chlorate, chloride and chlorite in water with low contamination ISO :1992 Water quality -- Determination of fluoride -- Part 1: Electrochemical probe method for potable and lightly polluted water ISO :1994 Water quality -- Determination of fluoride -- Part 2: Determination of inorganically bound total fluoride after digestion and distillation ISO 10523:1994 Water quality -- Determination of pH ISO 10530:1992 Water quality -- Determination of dissolved sulfide -- Photometric method using methylene blue ISO 10566:1994 Water quality -- Determination of aluminium -- Spectrometric method using pyrocatechol violet ISO 10695:2000 Water quality -- Determination of selected organic nitrogen and phosphorus compounds -- Gas chromatographic methods ISO 11083:1994 Water quality -- Determination of chromium(VI) -- Spectrometric method using 1,5-diphenylcarbazide ISO 11369:1997 Water quality -- Determination of selected plant treatment agents -- Method using high performance liquid chromatography with UV detection after solid-liquid extraction

17 ISO/TS 11370:2000 Water quality -- Determination of selected organic plant-treatment agents -- Automated multiple development (AMD) technique ISO :1997 Water quality -- Determination of benzene and some derivatives -- Part 1: Head-space gas chromatographic method ISO :1997 Water quality -- Determination of benzene and some derivatives -- Part 2: Method using extraction and gas chromatography ISO 11732:2005 Water quality -- Determination of ammonium nitrogen -- Method by flow analysis (CFA and FIA) and spectrometric detection ISO 11885:2007 Water quality -- Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) ISO :1997 Water quality -- Determination of nitrogen -- Part 1: Method using oxidative digestion with peroxodisulfate ISO/TR :1997 Water quality -- Determination of nitrogen -- Part 2: Determination of bound nitrogen, after combustion and oxidation to nitrogen dioxide, chemiluminescence detection ISO 11923:1997 Water quality -- Determination of suspended solids by filtration through glass-fibre filters ISO 11969:1996 Water quality -- Determination of arsenic -- Atomic absorption spectrometric method (hydride technique) ISO 12020:1997 Water quality -- Determination of aluminium -- Atomic absorption spectrometric methods ISO 13358:1997 Water quality -- Determination of easily released sulfide ISO 13395:1996 Water quality -- Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection

18 ISO/TR 13530:1997 Water quality -- Guide to analytical quality control for water analysis
ISO 14402:1999 Water quality -- Determination of phenol index by flow analysis (FIA and CFA) ISO 14403:2002 Water quality -- Determination of total cyanide and free cyanide by continuous flow analysis ISO 14911:1998 Water quality -- Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+ and Ba2+ using ion chromatography -- Method for water and waste water ISO 15061:2001 Water quality -- Determination of dissolved bromate -- Method by liquid chromatography of ions ISO 15089:2000 Water quality -- Guidelines for selective immunoassays for the determination of plant treatment and pesticide agents ISO 15586:2003 Water quality -- Determination of trace elements using atomic absorption spectrometry with graphite furnace ISO :2002 Water quality -- Digestion for the determination of selected elements in water -- Part 1: Aqua regia digestion ISO :2002 Water quality -- Digestion for the determination of selected elements in water -- Part 2: Nitric acid digestion ISO 15680:2003 Water quality -- Gas-chromatographic determination of a number of monocyclic aromatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and thermal desorption ISO :2003 Water quality -- Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) -- Part 1: Method by flow injection analysis (FIA) ISO :2003 Water quality -- Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) -- Part 2: Method by continuous flow analysis (CFA)

19 ISO 15682:2000 Water quality -- Determination of chloride by flow analysis (CFA and FIA) and photometric or potentiometric detection ISO 15705:2002 Water quality -- Determination of the chemical oxygen demand index (ST-COD) -- Small-scale sealed-tube method ISO 15913:2000 Water quality -- Determination of selected phenoxyalkanoic herbicides, including bentazones and hydroxybenzonitriles by gas chromatography and mass spectrometry after solid phase extraction and derivatization ISO 16264:2002 Water quality -- Determination of soluble silicates by flow analysis (FIA and CFA) and photometric detection ISO/TS 16489:2006 Water quality -- Guidance for establishing the equivalency of results ISO/TS 16489:2006/Cor 1:2006 ISO 16588:2002 Water quality -- Determination of six complexing agents -- Gas-chromatographic method ISO 16588:2002/Amd 1:2004 ISO 16590:2000 Water quality -- Determination of mercury -- Methods involving enrichment by amalgamation ISO :2004 Water quality -- Application of inductively coupled plasma mass spectrometry (ICP-MS) -- Part 1: General guidelines ISO :2003 Water quality -- Application of inductively coupled plasma mass spectrometry (ICP-MS) -- Part 2: Determination of 62 elements ISO 17353:2004 Water quality -- Determination of selected organotin compounds -- Gas chromatographic method

20 ISO 17495:2001 Water quality -- Determination of selected nitrophenols -- Method by solid-phase extraction and gas chromatography with mass spectrometric detection ISO 17852:2006 Water quality -- Determination of mercury -- Method using atomic fluorescence spectrometry ISO 17858:2007 Water quality -- Determination of dioxin-like polychlorinated biphenyls -- Method using gas chromatography/mass spectrometry ISO 17993:2002 Water quality -- Determination of 15 polycyclic aromatic hydrocarbons (PAH) in water by HPLC with fluorescence detection after liquid-liquid extraction ISO 18073:2004 Water quality -- Determination of tetra- to octa-chlorinated dioxins and furans -- Method using isotope dilution HRGC/HRMS ISO 18412:2005 Water quality -- Determination of chromium(VI) -- Photometric method for weakly contaminated water ISO 18856:2004 Water quality -- Determination of selected phthalates using gas chromatography/mass spectrometry ISO :2005 Water quality -- Determination of selected alkylphenols -- Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection ISO 20179:2005 Water quality -- Determination of microcystins -- Method using solid phase extraction (SPE) and high performance liquid chromatography (HPLC) with ultraviolet (UV) detection

21 ISO 22032:2006 Water quality -- Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge -- Method using extraction and gas chromatography/mass spectrometry ISO 22478:2006 Water quality -- Determination of certain explosives and related compounds -- Method using high-performance liquid chromatography (HPLC) with UV detection ISO 22743:2006 Water quality -- Determination of sulfates -- Method by continuous flow analysis (CFA) ISO 22743:2006/Cor 1:2007 ISO 23631:2006 Water quality -- Determination of dalapon, trichloroacetic acid and selected haloacetic acids -- Method using gas chromatography (GC-ECD and/or GC-MS detection) after liquid-liquid extraction and derivatization ISO 23913:2006 Water quality -- Determination of chromium(VI) -- Method using flow analysis (FIA and CFA) and spectrometric detection

22 ISO 6340:1995 Water quality -- Detection and enumeration of Salmonella
TC 147/SC 4 Microbiological methods ISO 6222:1999 Water quality -- Enumeration of culturable micro-organisms -- Colony count by inoculation in a nutrient agar culture medium ISO 6340:1995 Water quality -- Detection and enumeration of Salmonella ISO :1986 Water quality -- Detection and enumeration of the spores of sulfite-reducing anaerobes (clostridia) -- Part 1: Method by enrichment in a liquid medium ISO :1986 Water quality -- Detection and enumeration of the spores of sulfite-reducing anaerobes (clostridia) -- Part 2: Method by membrane filtration ISO 7704:1985 Water quality -- Evaluation of membrane filters used for microbiological analyses ISO :1998 Water quality -- Detection and enumeration of intestinal enterococci -- Part 1: Miniaturized method (Most Probable Number) for surface and waste water ISO :1998/Cor 1:2000 ISO :2000 Water quality -- Detection and enumeration of intestinal enterococci -- Part 2: Membrane filtration method ISO 8199:2005 Water quality -- General guidance on the enumeration of micro-organisms by culture ISO :2000 Water quality -- Detection and enumeration of Escherichia coli and coliform bacteria -- Part 1: Membrane filtration method

23 ISO :2000/Cor 1:2007 ISO :1990 Water quality -- Detection and enumeration of coliform organisms, thermotolerant coliform organisms and presumptive Escherichia coli -- Part 2: Multiple tube (most probable number) method ISO :1998 Water quality -- Detection and enumeration of Escherichia coli and coliform bacteria -- Part 3: Miniaturized method (Most Probable Number) for the detection and enumeration of E. coli in surface and waste water ISO :1998/Cor 1:2000 ISO 9998:1991 Water quality -- Practices for evaluating and controlling microbiological colony count media used in water quality tests ISO :1995 Water quality -- Detection and enumeration of bacteriophages -- Part 1: Enumeration of F-specific RNA bacteriophages ISO :2000 Water quality -- Detection and enumeration of bacteriophages -- Part 2: Enumeration of somatic coliphages ISO :2003 Water quality -- Detection and enumeration of bacteriophages -- Part 3: Validation of methods for concentration of bacteriophages from water ISO :2001 Water quality -- Detection and enumeration of bacteriophages -- Part 4: Enumeration of bacteriophages infecting Bacteroides fragilis ISO 11731:1998 Water quality -- Detection and enumeration of Legionella ISO :2004 Water quality -- Detection and enumeration of Legionella -- Part 2: Direct membrane filtration method for waters with low bacterial counts ISO/TR 13843:2000 Water quality -- Guidance on validation of microbiological methods

24 ISO 19458:2006 Water quality -- Sampling for microbiological analysis
ISO 15553:2006 Water quality -- Isolation and identification of Cryptosporidium oocysts and Giardia cysts from water ISO 16266:2006 Water quality -- Detection and enumeration of Pseudomonas aeruginosa -- Method by membrane filtration ISO 17994:2004 Water quality -- Criteria for establishing equivalence between microbiological methods ISO 17995:2005 Water quality -- Detection and enumeration of thermotolerant Campylobacter species ISO 19458:2006 Water quality -- Sampling for microbiological analysis

25 TC 147/SC 5 Biological methods
ISO 6341:1996 Water quality -- Determination of the inhibition of the mobility of Daphnia magna Straus (Cladocera, Crustacea) -- Acute toxicity test ISO 6341:1996/Cor 1:1998 ISO :1996 Water quality -- Determination of the acute lethal toxicity of substances to a freshwater fish [Brachydanio rerio Hamilton-Buchanan (Teleostei, Cyprinidae)] -- Part 1: Static method ISO :1996 Water quality -- Determination of the acute lethal toxicity of substances to a freshwater fish [Brachydanio rerio Hamilton-Buchanan (Teleostei, Cyprinidae)] -- Part 2: Semi-static method ISO :1996 Water quality -- Determination of the acute lethal toxicity of substances to a freshwater fish [Brachydanio rerio Hamilton-Buchanan (Teleostei, Cyprinidae)] -- Part 3: Flow-through method ISO 7827:1994 Water quality -- Evaluation in an aqueous medium of the "ultimate" aerobic biodegradability of organic compounds -- Method by analysis of dissolved organic carbon (DOC) ISO 7828:1985 Water quality -- Methods of biological sampling -- Guidance on handnet sampling of aquatic benthic macro-invertebrates ISO 8192:2007 Water quality -- Test for inhibition of oxygen consumption by activated sludge for carbonaceous and ammonium oxidation ISO 8265:1988 Water quality -- Design and use of quantitative samplers for benthic macro-invertebrates on stony substrata in shallow freshwaters

26 ISO :2000 Water quality -- Biological classification of rivers -- Part 1: Guidance on the interpretation of biological quality data from surveys of benthic macroinvertebrates ISO :2000 Water quality -- Biological classification of rivers -- Part 2: Guidance on the presentation of biological quality data from surveys of benthic macroinvertebrates ISO 8692:2004 Water quality -- Freshwater algal growth inhibition test with unicellular green algae ISO 9391:1993 Water quality -- Sampling in deep waters for macro-invertebrates -- Guidance on the use of colonization, qualitative and quantitative samplers ISO 9408:1999 Water quality -- Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium by determination of oxygen demand in a closed respirometer ISO 9439:1999 Water quality -- Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium -- Carbon dioxide evolution test ISO 9509:2006 Water quality -- Toxicity test for assessing the inhibition of nitrification of activated sludge microorganisms ISO 9887:1992 Water quality -- Evaluation of the aerobic biodegradability of organic compounds in an aqueous medium -- Semi-continuous activated sludge method (SCAS) ISO 9888:1999 Water quality -- Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium -- Static test (Zahn-Wellens method) ISO 10229:1994 Water quality -- Determination of the prolonged toxicity of substances to freshwater fish -- Method for evaluating the effects of substances on the growth rate of rainbow trout (Oncorhynchus mykiss Walbaum (Teleostei, Salmonidae)) ISO 10253:2006 Water quality -- Marine algal growth inhibition test with Skeletonema costatum and Phaeodactylum tricornutum

27 ISO 10634:1995 Water quality -- Guidance for the preparation and treatment of poorly water-soluble organic compounds for the subsequent evaluation of their biodegradability in an aqueous medium ISO 10706:2000 Water quality -- Determination of long term toxicity of substances to Daphnia magna Straus (Cladocera, Crustacea) ISO 10707:1994 Water quality -- Evaluation in an aqueous medium of the "ultimate" aerobic biodegradability of organic compounds -- Method by analysis of biochemical oxygen demand (closed bottle test) ISO 10708:1997 Water quality -- Evaluation in an aqueous medium of the ultimate aerobic biodegradability of organic compounds -- Determination of biochemical oxygen demand in a two-phase closed bottle test ISO 10712:1995 Water quality -- Pseudomonas putida growth inhibition test (Pseudomonas cell multiplication inhibition test) ISO :1998 Water quality -- Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri (Luminescent bacteria test) -- Part 1: Method using freshly prepared bacteria ISO :1998 Water quality -- Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri (Luminescent bacteria test) -- Part 2: Method using liquid-dried bacteria ISO :1998 Water quality -- Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri (Luminescent bacteria test) -- Part 3: Method using freeze-dried bacteria ISO 11733:2004 Water quality -- Determination of the elimination and biodegradability of organic compounds in an aqueous medium -- Activated sludge simulation test ISO 11734:1995 Water quality -- Evaluation of the "ultimate" anaerobic biodegradability of organic compounds in digested sludge -- Method by measurement of the biogas production

28 ISO 12890:1999 Water quality -- Determination of toxicity to embryos and larvae of freshwater fish -- Semi-static method ISO :2003 Water quality -- Determination of inhibition of gas production of anaerobic bacteria -- Part 1: General test ISO :2003 Water quality -- Determination of inhibition of gas production of anaerobic bacteria -- Part 2: Test for low biomass concentrations ISO 13829:2000 Water quality -- Determination of the genotoxicity of water and waste water using the umu-test ISO 14442:2006 Water quality -- Guidelines for algal growth inhibition tests with poorly soluble materials, volatile compounds, metals and waste water ISO :2002 Water quality -- Evaluation of the aerobic biodegradability of organic compounds at low concentrations -- Part 1: Shake-flask batch test with surface water or surface water/sediment suspensions ISO :2002 Water quality -- Evaluation of the aerobic biodegradability of organic compounds at low concentrations -- Part 2: Continuous flow river model with attached biomass ISO 14593:1999 Water quality -- Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium -- Method by analysis of inorganic carbon in sealed vessels (CO2 headspace test) ISO 14669:1999 Water quality -- Determination of acute lethal toxicity to marine copepods (Copepoda, Crustacea) ISO 15088:2007 Water quality -- Determination of the acute toxicity of waste water to zebrafish eggs (Danio rerio) ISO/TR 15462:2006 Water quality -- Selection of tests for biodegradability ISO 15522:1999 Water quality -- Determination of the inhibitory effect of water constituents on the growth of activated sludge microorganisms

29 ISO 16221:2001 Water quality -- Guidance for determination of biodegradability in the marine environment ISO 16240:2005 Water quality -- Determination of the genotoxicity of water and waste water -- Salmonella/microsome test (Ames test) ISO 16665:2005 Water quality -- Guidelines for quantitative sampling and sample processing of marine soft-bottom macrofauna ISO 16712:2005 Water quality -- Determination of acute toxicity of marine or estuarine sediment to amphipods ISO 18749:2004 Water quality -- Adsorption of substances on activated sludge -- Batch test using specific analytical methods ISO 19493:2007 Water quality -- Guidance on marine biological surveys of hard-substrate communities ISO 20079:2005 Water quality -- Determination of the toxic effect of water constituents and waste water on duckweed (Lemna minor) -- Duckweed growth inhibition test ISO/TS 20281:2006 Water quality -- Guidance on statistical interpretation of ecotoxicity data ISO :2006 Water quality -- Evaluation of genotoxicity by measurement of the induction of micronuclei -- Part 1: Evaluation of genotoxicity using amphibian larvae ISO :2006 Water quality -- Evaluation of genotoxicity by measurement of the induction of micronuclei -- Part 2: Mixed population method using the cell line V79 ISO :2007 Water quality -- Biochemical and physiological measurements on fish -- Part 1: Sampling of fish, handling and preservation of samples ISO/TS :2007 Water quality -- Biochemical and physiological measurements on fish -- Part 2: Determination of ethoxyresorufin-O-deethylase (EROD)

30 TC 147/SC 6 Sampling (general methods)
ISO :2006 Water quality -- Sampling -- Part 1: Guidance on the design of sampling programmes and sampling techniques ISO :2003 Water quality -- Sampling -- Part 3: Guidance on the preservation and handling of water samples ISO :1987 Water quality -- Sampling -- Part 4: Guidance on sampling from lakes, natural and man-made ISO :2006 Water quality -- Sampling -- Part 5: Guidance on sampling of drinking water from treatment works and piped distribution systems ISO :2005 Water quality -- Sampling -- Part 6: Guidance on sampling of rivers and streams ISO :1993 Water quality -- Sampling -- Part 7: Guidance on sampling of water and steam in boiler plants ISO :1993 Water quality -- Sampling -- Part 8: Guidance on the sampling of wet deposition ISO :1992 Water quality -- Sampling -- Part 9: Guidance on sampling from marine waters ISO :1992 Water quality -- Sampling -- Part 10: Guidance on sampling of waste waters

31 ISO 5667-11:1993 Water quality -- Sampling -- Part 11: Guidance on sampling of groundwaters
ISO :1995 Water quality -- Sampling -- Part 12: Guidance on sampling of bottom sediments ISO :1997 Water quality -- Sampling -- Part 13: Guidance on sampling of sludges from sewage and water treatment works ISO :1998 Water quality -- Sampling -- Part 14: Guidance on quality assurance of environmental water sampling and handling ISO :1999 Water quality -- Sampling -- Part 15: Guidance on preservation and handling of sludge and sediment samples ISO :1998 Water quality -- Sampling -- Part 16: Guidance on biotesting of samples ISO :2000 Water quality -- Sampling -- Part 17: Guidance on sampling of suspended sediments ISO :2001 Water quality -- Sampling -- Part 18: Guidance on sampling of groundwater at contaminated sites ISO :2004 Water quality -- Sampling -- Part 19: Guidance on sampling of marine sediments

32 Normalización a nivel local

33 Esquema tradicional de una norma
IRAM Directiva 1- Redacción y presentación de las normas IRAM

34 Ejemplo de esquema de una norma
PREFACIO OBJETO Y CAMPO DE APLICACIÓN DOCUMENTOS NORMATIVOS PARA CONSULTA DEFINICIONES INTERFERENTES REACTIVOS / INSTRUMENTAL CALIBRACION MUESTREO / PROCEDIMIENTO CÁLCULOS MANEJO Y GESTION DE RESIDUOS SEGURIDAD Y SALUD ANEXOS REFERENCIAS BIBLIOGRAFICAS

35 Comité de Calidad Ambiental IRAM
Subcomité Ecotoxicología Subcomité Calidad de Aire Subcomité Calidad de Suelo Subcomité Calidad del agua de Análisis Biológicos Subcomité Calidad de Agua – Análisis Químicos Subcomité Gestión de la Calidad de Serv. de Abastecim. de Agua Potable y Sist. de Aguas Residuales Subcomité de Acciones Correctivas Basadas en Riesgo (ACBR)

36 SC 1 Calidad del agua Análisis Químicos Buenos Aires
ISO / TC 147 SC 2 Calidad del agua de Análisis Biológicos SC Ecotoxicología SC 1 Calidad del agua Análisis Químicos Buenos Aires

37 SC1- Calidad del Agua de Análisis Químicos
Determinación de constituyentes del agua Determinación de parámetros característicos Muestreo Utilización de diversos métodos y técnicas de análisis

38 SC1 - Calidad del Agua de Análisis Químicos
Normas IRAM publicadas IRAM Determinación de la demanda química de oxígeno (DQO) por la técnica del dicromato IRAM Determinación de la demanda química de oxígeno (DQO) Parte 2: Método colorimétrico con reflujo cerrado IRAM Determinación de cianuro. Parte 1: Determinación de cianuro total IRAM Determinación de cianuro. Parte 2: Determinación de cianuro fácilmente liberable IRAM Determinación de turbidez

39 IRAM 29012-1. Muestro. Parte 1: Directivas Generales para el diseño de programas de muestreo
IRAM Muestreo de Aguas residuales IRAM Muestreo. Parte 11: Directivas para el muestreo de aguas subterráneas IRAM Muestreo. Parte 14: Directivas sobre aseguramiento de la calidad del muestreo y manipulación de agua IRAM Muestreo. Directivas para la preservación y manipulación de muestras de barros y sedimentos IRAM Muestreo. Directivas generales sobre técnicas IRAM Muestreo. Parte 3: Guía para la preservación y manipulación de las muestras IRAM Muestreo. Parte 4: Directivas para el muestreo de aguas de lagos naturales y artificiales

40 IRAM Muestreo. Parte 5: Guía sobre muestreo de agua potable y de aguas utilizadas para el procesamiento de alimentos y bebidas IRAM Parte 7: Guía para el muestreo de agua y vapor en calderas IRAM Determinación de cromo. Parte 1: Método de l difenilcarbazida IRAM Determinación de cromo. Parte 2: Método de espectrometría de absorción atómica IRAM Determinación de la demanda bioquímica de oxígeno después de n días (DBOn). Parte 1: Método de dilución y siembra con alil tioudea IRAM Determinación de la demanda bioquímica de oxígeno después de n días. Parte 2: Método para muestras que no requieren dilución IRAM Lixiviación. Procedimiento de extracción y ensayo de integridad estructural IRAM Determinación de bifenilos policlorados (PCB). Parte 1: Preparación de la muestra por extracción líquido – líquido en ampolla de decantación

41 Normas IRAM publicadas: 25
IRAM Determinación de bifenilos policlorados (PCB) Parte 2: Limpieza del extracto con ácido sulfúrico permanganato IRAM Determinación de bifenilos policlorados (PCB).Parte 3: Cromatografía gaseosa IRAM Determinación de tensioactivos aniónicos por medición del índice de azul de metileno IRAM Determinación de sulfuro disuelto. Parte 3: Método fotométrico utilizando azul de metileno Normas IRAM publicadas: 25

42 SC1 - Calidad del Agua de Análisis Químicos
Normas en Estudio IRAM Determinación de fluoruro. Método de sonda electroquímica para agua potable y agua levemente contaminada Especifica un método para la determinación de fluoruro disuelto en agua potable y levemente contaminada, y en ciertas aguas superficiales. usando una técnica electroquímica. Apropiado para concentraciones de fluoruro desde 0,2 mg/L a 2.0 g/L No es apropiado para aguas residuales y efluentes industriales

43 IRAM 29031. Determinación de arsénico. Método de
IRAM Determinación de fluoruros. Parte 2: Determinación de fluoruro total inorgánico luego de la digestión y destilación. Esta norma comenzará a tratarse en reuniones próximas IRAM Determinación de arsénico. Método de espectrometría de absorción atómica (técnica de hidruro) Especifica un método para la determinación de arsénico en aguas de bebida, aguas subterráneas y aguas subterráneas y aguas superficiales Rango de concentración de arsénico de 1 μg/l a 10 μg/l Se basa en la medición de absorción atómica del arsénico generado por descomposición térmica del hidruro de arsénico (III) .

44 IRAM Lixiviación. Procedimiento de lixiviación para la evaluación de características de toxicidad (PLCT) (EA 7) Establece el procedimiento para determinar la movilidad de analitos orgánicos e inorgánicos, presentes en los residuos líquidos, sólidos y multifásicos. No es necesario aplicar este método cuando un análisis global de residuos demuestra que no están presentes analitos individuales o que se encuentran en una concentración que no excede los niveles regulados IRAM Evaluación estadística de la función de calibración lineal para métodos analíticos instrumentales (E 2) Describe los pasos a seguir para evaluar las características estadísticas de la función de calibración lineal Aplicable a métodos analíticos instrumentales que requieren calibración

45 SC 2 Calidad del agua de Análisis Biológicos
Muestreo Medición Registro Características biológicas del agua Muestreo y análisis de contaminantes en efluentes líquidos

46 SC 2 Calidad del agua de Análisis Biológicos
Norma Título Publicada IRAM 29006 Determinación de la demanda bioquímica de oxígeno después de 5 d (DBO5), por dilución y siembra IRAM 29008 Determinación de O disuelto. Método yodométrico. IRAM 29009 Determinación del oxígeno disuelto. Método electroquímico de la sonda IRAM 29012 Muestreo. Parte 9. Directivas para el muestreo de aguas marinas y de estuarios

47 Norma Título Publicada IRAM Detección y recuento de Escherichia coli y bacterias coliformes. Parte 1: Método de filtración por membrana IRAM Detección y enumeración de organismos coliformes, organismos coliformes termoto-lerantes y Escherichia coli presuntiva. Parte 2: Método de tubos múltiples (número más probable). IRAM 29122 Recuento de microorganismos cultivables. Recuento de colonias en un medio nutritivo agarizado. IRAM 29198 Método de evaluación y control de medios de cultivo usados para el recuento de colonias en ensayos de calidad de aguas.

48 Norma Título Estado IRAM 29104 Detección y recuento de Escherichia coli y bacterias coliformes. Parte 1: Método de filtración por membrana En estudio DP IRAM 29108 Detección y recuento de Pseudomonas aeruginosa. Método por filtración de membrana. Su presencia es considerada como indicador de las condiciones higiénico sanitarias de los sistemas de almacenamiento y distribución de agua En estudio EA5 IRAM Detección y enumeración de organismos coliformes, organismos coliformes termotolerantes y Escherichia coli presuntiva. Parte 2: Método de tubos múltiples (número más probable). A iniciar estudio

49 SC 2 Ecotoxicología Muestreo Medición Registro
Características ecotoxicológicas del agua Muestreo y análisis de contaminantes en efluentes acuosos

50 SC 2 Ecotoxicología Norma Título Publicada IRAM 29012-16
Calidad ambiental Muestreo. Parte 16. Guía para el bioensayo de muestras. IRAM 29111 Método de ensayo de inhibición del crecimiento de algas verdes unicelulares de agua dulce. IRAM 29130 Deteminación de la inhibición de la movilidad de Daphnia magna Straus (Cladocera, Crustacea). Ensayo de toxicidad aguda (2004)

51 Norma Título Estado IRAM 29112 Deteminación de la toxicidad letal aguda de sustancias en peces de agua dulce. Método semiestático En estudio E1a IRAM 29114 Método de ensayo de toxicidad aguda con semillas de lechuga ( Lactuca sativa L.)EA5 IRAM 29115 Determinación del efecto inhibidor de muestras de agua sobre la luminiscencia de Vibrio fischeri (ensayo de bacterias luminiscentes). Método utilizando bacterias liofilizadas. A iniciar

52 Comparativa normativa nacional/internacional
Parámetros IRAM ISO Observaciones UNE DQO 6060:1989 Determination of the chamical oxygen demand 77004:2002 Determinación de la demanda química de oxígeno (DQO). Método del docromato DBO 29006 5815-1:2003 Determination of biochemical oxygen demand after n days (BODn)- Part 1: Dilution and seeding method with allylthiourea addition - 5815-2:2003 Dtermination of biochemical oxygen demand after n days (BODn)- Part 2: Method for undiluted samples Sólidos Suspendidos Totales C. fenólicos clorados[1] 6439:1990 Determination of phenol index- 4-Aminoantipyrine spectrometric methods after destilation.

53 Determination of phosphorus- Ammonium molybdate sprectrometric method
Parámetros IRAM ISO Observaciones UNE pH 29130 - 77078:2002 Especificaciones técnicas de carácter general para los instrumentos de medida en continuo de pH en vertidos industriales Nitrógeno total 22406 Nitrógeno amoniacal Fósforo 6878:2004 Determination of phosphorus- Ammonium molybdate sprectrometric method Detergentes 25614 Color 29087 ISO 7887:1994 Examination and determination of colour Otros Parámetros Temperatura Sólidos Sedimen. 2 horas 29105 Sulfuros S.S.E.E.

54 Hidrocarburos Totales
Parámetros IRAM ISO Observaciones UNE Cianuros 6703-1: 1984 Determination of cyanide- Part 1: Determination of total cyanide - 6703-2: 1984 Determination of cyanide- Part 2: Determination of easily liberatable cyanide 6703-3: 1984 Determination of cyanide- Part 3: Determination of cyanogen chloride Hidrocarburos Totales 29033 Cloro Libre 7393-2:1995 Determination of free chlorine and total chlorine- Part 2 Colorimetric method using N,N- diethyl-1,4-phenylenediamine, for routine control purposes. 7393-3:1990 Determination of free chlorine and total chlorine- Part 3 Iodometric titration method for the determination of total chlorine. Coliformes Fecales S.A.A.M. Hierro (soluble) 6332:1998 Determination of iron. Spectrometric method using 1,10-phenanthroline Manganeso (soluble) 6333:1986 Determination of manganeso- Formaldoxime spectrometric method.

55 Plaguicidas Organoclorados Plaguicidas Organofosforados
Parámetros IRAM ISO Observaciones UNE Cinc - Níquel Cromo Total Cromo Hexavalente Cadmio 5961:1994 Determination of cadmium by atomic absorption spectrometry Mercurio 5666:1999 Cobre Aluminio Arsénico 29019 29031 Bario Boro Cobalto Selenio 5663:1984 Plomo Plaguicidas Organoclorados 6468:1996 Determination of certain organochlorine insecticidas, polychlorinated biphenyls and chlorobenzenes- Gas chromatographic method after liquid-liquid extraction Plaguicidas Organofosforados Nitrógeno Orgánico

56 Determination of ammonium- Part 1: Manual spectrometric method
Parámetros IRAM ISO Observaciones UNE Amoníaco - 5664:1984 7150-1:1984 Determination of ammonium- Part 1: Manual spectrometric method Alquil Benceno Sulfonato (ABS) Plata Demanda de Cloro Cromo Trivalente Estroncio Radio Radiaciones Beta Cloro residual OD O.C. del MnO4K Sustancias Solubles en éter etílico Relación de absorción de sodio Conductividad ISO 7888:1985 Determination of electrical conductivity Dureza Fluoruros Turbiedad 7027:1999 Determination of turbidity Sólidos disueltos totales Sulfatos

57 Conclusión final Comunicación Participación activa
Detectar necesidades y tendencias Trabajo en conjunto

58 Muchas Gracias!!! Contacto Ing. Juan Ojea Espil
Gerencia Energía y Asuntos Ambientales Dirección de Normalización, IRAM Mail: Tel: Web: